Abstract
The solubilities of copper hydroxide Cu(OH)2, copper oxide CuO, atacamite Cu(OH)1.5Cl0.5, malachite Cu2(OH)2CO3 and chessylite Cu3(OH)2(CO3)2 in an ammonia-ammonium chloride-water solution were calculated using an exponential computation method based on both mass balance and charge balance equations. The range of stability of each solid phase was also established. A group of experiments were designed to validate the veracity of the results of the thermodynamic calculation.
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