Abstract
For this article, a number of thermodynamic properties for MCl (M = Na, K, Rb, Cs) in tetramethylurea (TMU)-water ternary systems were investigated through potentiometric method at the temperature of 298.2 K. To fit experiment data, the Pitzer equation and the extended Debye-Hückel equation were used. The mean activity coefficients, together with excess Gibbs free energy, osmotic coefficients and standard solubility product of ternary systems are calculated. The variation of these properties in this εr-decreasing co-solvent (TMU-H2O) is discussed from the aspect of ion radius, relative permittivity, ion-ion interactions and ion-solvent in the solution.
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