Abstract

Excess molar isobaric heats capacities C P E of the mixtures of { x 1,3-dioxane or 1,4-dioxane+(1− x) 2,2, 4-trimethylpentane, or tetrachloroethene, or benzene} were measured at 298.15 K. C P E curves for both 2,2,4-trimethylpentane systems were ‘W shaped’ which was discussed previously by Patterson et al. The values of C P E for both tetrachloroethene systems were positive and also that of 1,3-dioxane+benzene system was positive. The values of C P E of 1,4-dioxane+benzene system changed the sign from positive to negative with increase of mole fraction of dioxane. ‘W-shaped’ C P E for the 2,2,4-trimethylpentane systems suggests the existence of non-randomness ascribed to dipolar interaction.

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