Abstract
Densities and refractive indices for (acetone+ methanol +2-butanol) and the enclosed binary systems (acetone+2-butanol) and (methanol+2-butanol) have been measured atT=298.15;K and atmospheric pressure. Values of densities, refractive indices, excess molar volumes, and changes of refractive indices on mixing were compared with the results obtained by different estimation methods. Parameters of analytical expressions which represent the composition dependence of physical properties and excess values are reported. The binary mixtures described in this paper show positive deviations in the derived properties, as well as changes of refractive indices on mixing for the ternary mixture, while excess molar volumes show negative behaviour at low compositions of the heavy alcohol. Results of these measurements have been applied to calculate partial excess molar volumes and limiting partial excess molar volumes at infinite dilution in binary mixtures, which can be applied as a basis for understanding the molecular interactions in (alcohol + alcohol) and (alcohol + ketone) mixtures according to sign and trend.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
