Abstract
1. The molar heats and entropies of solution of certain alkyl derivatives and oxygen-containing compounds of silicon, germanium, and tin in nonpolar (apiezon L) and polar (polyethylene glycol sebacate, SKTFT-50) stationary phases were determined. 2. Equations were proposed for the calculation of the molar heats of solution of the investigated heteroorganic compounds (HOC) as a function of the number of carbon and oxygen atoms in the molecule. 3. The presence of a linear correlation between the relative values of the molar enthalpies and entropies of solution of spherical molecules of HOC was demonstrated. 4. Equations were proposed for the calculation of the molar entropies of solution of the investigated HOC as a function of the number of carbon atoms in the molecule.
Published Version
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