Thermochemical processing of a South African ultrafine coal fly ash using ammonium sulphate as extracting agent for aluminium extraction

Abstract

South African coal fly ash represents an untapped secondary resource of aluminium. Continuous research is conducted to develop suitable chemical and/or geometallurgical processes for aluminium extraction, preferably accompanied by minimal silicon extraction. The thermochemical treatment of a South African ultrafine coal fly ash was investigated to test the feasibility of recovering aluminium using ammonium sulphate, a widely available, low-cost, recyclable chemical agent. The optimum processing conditions were determined to be a temperature of 500°C and a fly ash to ammonium sulphate weight ratio of 2:6 when a reaction time of 1h was used. Water leaching of the reaction product obtained under these conditions resulted in the selective recovery of 95.0% aluminium from the amorphous phase, with <0.6% Si extracted. Mullite was unlikely to have reacted with the extracting agent. Except for Si, the process was not element-selective, but the extraction of iron could be minimized by increasing the treatment temperature to 600°C without compromising Al extraction. Thermochemical treatment using ammonium sulphate may therefore represent a promising technology for extracting aluminium from coal fly ash, which could be subsequently converted to value-added products such as alumina.