Abstract
The thermal behaviour of sodium acetate trihydrate (NaAc · 3H2O) was investigated by DTA, Q-TG and measurements of the solubility properties. The nucleation efficiency of Na4P2O7 · 10H2O for the crystallization of NaAc · 3H2O melts is not stable over long periods. Stratification can be ascribed to the formation of anhydrous sodium acetate in the supercooled melts. Under static heat storage conditions, NaAc · 3H2O and Na4P2O7 · 10H2O do not exhibit stable behaviour.
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