Abstract
Organolanthanide complexes inside the nanochannels of zeolite L crystals have been synthesized using a ship in a bottle procedure by inserting 2,2-bipyridine (bpy) from gas phase into the nanochannels of Ln 3+-zeolite L crystals; Ln 3+ = Tb 3+ or Eu 3+. The resulting Ln 3+(bpy) n -zeolite L host-guest materials were characterized by FT–IR and photoluminescence spectroscopy, by thermogravimetry and by SEM. The encapsulated luminescent organolanthanide complexes show remarkably increased thermal stability.
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