Thermally driven MnCl2[sbnd]NH4Cl resorption cycle for seasonal thermal management of urban buildings

Abstract

The frequency of extreme weather conditions caused by global greenhouse gas emissions has led to a significant increase in energy consumption for refrigeration and heating supply in urban buildings. However, conventional sensible and latent heat storage technologies hold low thermal energy storage density and short-term energy storage capabilities. Additionally, electrically driven compression refrigeration with non-negligible global warming potential (GWP) is unsuited to high ambient temperatures in summer. We propose an advanced strategy, adopting the MnCl2NH4Cl resorption cycle to achieve efficient desorption refrigeration of NH4Cl and resorption heating supply of MnCl2 under seasonal conditions. Experimental results have demonstrated that our proof-of-concept system can output 70 °C heat with a thermal energy storage density of 166.2 kJ·kg−1, providing continuous heating for 30.5 min under the winter ambient temperature of 10 °C. Moreover, COPref remained at 0.589 for continuous indoor refrigeration lasting 58.5 min under summer ambient and refrigeration temperatures of around 30 °C and 2 °C, respectively. This exceptional adaptability to ambient temperatures enables efficient adjustment of urban building comfort. Our work presents a promising zero-carbon pathway for replacing conventional fossil fuels employed in the thermal management of urban buildings with solar energy.