Abstract

To gain better insight into the thermal state and composition of the lithospheric mantle beneath the Upper Muna kimberlite field (Siberian craton), a suite of 323 clinopyroxene xenocrysts and 10 mantle xenoliths from the Komsomolskaya-Magnitnaya (KM) pipe have been studied. We selected 188 clinopyroxene grains suitable for precise pressure (P)-temperature (T) estimation using single-clinopyroxene thermobarometry. The majority of P-T points lie along a narrow, elongated field in P-T space with a cluster of high-T and high-P points above 1300 °C, which deviates from the main P-T trend. The latter points may record a thermal event associated with kimberlite magmatism (a “stepped” or “kinked” geotherm). In order to eliminate these factors, the steady-state mantle paleogeotherm for the KM pipe at the time of initiation of kimberlite magmatism (Late Devonian–Early Carboniferous) was constrained by numerical fitting of P-T points below T = 1200 °C. The obtained mantle paleogeotherm is similar to the one from the nearby Novinka pipe, corresponding to a ~34–35 mW/m2 surface heat flux, 225–230 km lithospheric thickness, and 110–120 thick “diamond window” for the Upper Muna field. Coarse peridotite xenoliths are consistent in their P-T estimates with the steady-state mantle paleogeotherm derived from clinopyroxene xenocrysts, whereas porphyroclastic ones plot within the cluster of high-T and high-P clinopyroxene xenocrysts. Discrimination using Cr2O3 demonstrates that peridotitic clinopyroxene xenocrysts are prevalent (89%) among all studied 323 xenocrysts, suggesting that the Upper Muna mantle is predominantly composed of peridotites. Clinopyroxene-poor or -free peridotitic rocks such as harzburgites and dunites may be evident at depths of 140–180 km in the Upper Muna mantle. Judging solely from the thermal considerations and the thickness of the lithosphere, the KM and Novinka pipes should have excellent diamond potential. However, all pipes in the Upper Muna field have low diamond grades (<0.9, in carats/ton), although the lithosphere thickness is almost similar to the values obtained for the high-grade Udachnaya and Mir pipes from the Daldyn and Mirny fields, respectively. Therefore, other factors have affected the diamond grade of the Upper Muna kimberlite field.

Highlights

  • Mantle-derived xenoliths and xenocrysts from kimberlites provide direct information about the composition and thermal state of the lithospheric mantle underlying the ancient cratons at time of kimberlite eruption [1,2,3,4,5,6,7,8]

  • The advantages of the second approach are as follows: (1) it can be used in cases where mantle xenoliths are absent or rare, e.g., due to secondary alteration; (2) xenocrysts are routinely obtained during diamond exploration; (3) it requires fewer analytical resources because each mineral grain is assumed to represent one mantle xenolith with an inferred mineralogy, for instance, single-clinopyroxene thermobarometry requires 3 or 4 times fewer microprobe analyses than conventional thermobarometry using mineral pairs; (4) its relative cheapness and efficiency makes it possible to obtain a statistically meaningful number of P-T points, which is very important for robust estimation of the paleogeotherm

  • The common approach used to characterize the thermal state of the lithospheric mantle, used by petrologists for years, is a graphical comparison of the P-T data for mantle xenoliths and xenocrysts to the petrologists for years, is a graphical comparison of the P-T data for mantle xenoliths and xenocrysts reference geotherms characterized in terms of surface heat flow [68]

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Summary

Introduction

Mantle-derived xenoliths and xenocrysts from kimberlites provide direct information about the composition and thermal state of the lithospheric mantle underlying the ancient cratons at time of kimberlite eruption [1,2,3,4,5,6,7,8]. The common petrological approach to constraining the mantle paleogeotherm beneath cratons is based on the calculation of the P-T conditions of equilibration for mantle xenoliths using thermobarometry based on the exchange of components between multiple minerals [6,17,18,19,20,21,22]. Another option is to use P-T data obtained from mantle xenocrysts, which represent single grains of disintegrated mantle xenoliths [2,15,16,23]. The advantages of the second approach are as follows: (1) it can be used in cases where mantle xenoliths are absent or rare, e.g., due to secondary alteration; (2) xenocrysts are routinely obtained during diamond exploration; (3) it requires fewer analytical resources because each mineral grain is assumed to represent one mantle xenolith with an inferred mineralogy, for instance, single-clinopyroxene thermobarometry requires 3 or 4 times fewer microprobe analyses than conventional thermobarometry using mineral pairs; (4) its relative cheapness and efficiency (only one mineral is used in the P-T calculations) makes it possible to obtain a statistically meaningful number of P-T points, which is very important for robust estimation of the paleogeotherm

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