Thermal stability of pure bcc Zr fabricated by high pressure torsion

Abstract

Recently pure omega plus bcc Zr was fabricated for the first time through the simultaneous application of compression and shear to pure alpha Zr by high pressure torsion. This phase was found to be stable under ambient conditions after processing. Here the thermal stability of the pure bcc Zr thus fabricated is analyzed using differential scanning calorimetry (DSC), in-situ X-ray diffraction at high temperature and transmission electron microscopy (TEM). Our results show that the temperature of the reverse transformation of the bcc phase is close to that of the omega phase. The presence of a mixed structure formed by alternating nanolaminates of the omega and the bcc phases might play a key role in the retention of these two phases at ambient pressure and temperature.