Abstract

The thermal stability of the metastable solid solutions obtained by implantation of Au- and Pb-ions in Fe single crystals at room temperature was studied by the channeling and backscattering technique. The maximum observed substitutional concentration in as-implanted crystals was 7 at.% in the case of Au and 3 at.% in the case of Pb. Equilibrium phase diagrams show that Au is soluble whereas Pb is insoluble in Fe. The precipitation and diffusion of the implanted species started at 450°C. The observed Au and Pb transport towards the surface at this temperature is probably due to the vacancy assisted migration. Pb-atoms are lost at the surface by sublimation. Au-atoms agglomerate at the surface. These Au precipitates act as a source for the observed in-diffusion of Au at higher temperatures with an activation energy of about 3 eV.

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