Abstract
A study of the thermal decomposition of crystal hydrates of decavanadates confirmed the stabilizing role of the crystal water in their structures. The original structure is destroyed after dehydration, and lower condensed vanadates and oxides of vanadium are formed. The course of thermal decomposition of the decavanadates depends on the bonding properties of the concrete elements present. The ability of a given element to form a certain type of vanadate, the thermal stability and the stoichiometry of the original compound are the main factors influencing the composition of the products of thermal decomposition of the vanadates studied.
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