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Abstract
Data are presented on the thermal oxidation of (V2O5 + PbO)/InP structures which demonstrate that the combined effect of the oxides deposited by magnetron sputtering does not follow the additivity rule and that this behavior is due to the formation of a quasi-liquid phase (maximum) and lead vanadate (minimum) (IR spectroscopy, Auger electron spectroscopy). The effective activation energy for the oxidation of the (V2O5 + PbO)/InP structures is shown to systematically decrease with increasing initial vanadium oxide content. The oxidation of the structures follows a partially catalytic mechanism, with V2O5 acting as a catalyst (oxidation kinetics, IR spectroscopy, ultrasoft X-ray emission spectroscopy).
Published Version
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