Thermal insulating and mechanical properties of high entropy pyrochlore oxide ceramic with hierarchical porous structures

Abstract

High entropy pyrochlore oxide ceramics with hierarchical porous structures were prepared by coprecipitation, freeze-casting, and press-less sintering methods. In the fabrication process, a Ca2+-crosslinked alginate network was utilized to control the growth of ice crystals, resulting in uniformly dispersed micro-scale circular pores. The submicron pores were formed in the high entropy oxide ceramic during the press-less sintering method. The XRD was employed to explore the phase of the high entropy pyrochlore oxide ceramic. The porous structures of high-entropy ceramic were analyzed through the discussion of microstructure and pore size distribution. The tests show that the prepared series of ceramics with high porosity have optional compressive strength and thermal insulation properties. The high entropy oxide ceramic (La0.2Y0.2Gd0.2Sm0.2Nd0.2)2Zr2O7 with hierarchical porous structures possess moderate density (0.4 g/cm3) and low thermal conductivity (0.04 W m−1 K−1). The excellent comprehensive performance makes the porous high entropy oxide ceramic could be applied as a thermal insulating material.