Abstract

Two polyurethane–epoxy maleate of bisphenol A semi-interpenetrating polymer networks were synthesized and their thermal behavior studied. The data obtained by thermogravimetry showed that the decomposition of the tested samples is complex, occurs in three steps, and depends on the degree of crosslinking. The main decomposition takes place between 290 and 480 °C, with weight losses between 62 and 66%. The apparent thermal stability of the sample synthesized with a low content of epoxy maleate of bisphenol-A (11.11 wt%) is lower compared with polyurethane, while the sample with high content of epoxy maleate of bisphenol-A (27.3 wt%) shows a higher stability.

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