The effect of citric acid concentrations on the mechanical, thermal, and structural properties of starch edible films

Abstract

SummaryThis study investigated the effects of citric acid on the properties of edible tapioca starch films plasticised with glycerol. These films were formed using 5% tapioca (w/w of water); 1%, 3%, 5%, 7% and 9% citric acid (w/w of starch); and 2.2% glycerol (w/w of water). Native starch films formed using 5% tapioca and 2.2% glycerol were used as the control. The properties tested included the degree of crosslinking, thermal stability, crystallinity and mechanical properties. These were evaluated using Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR‐FTIR), X‐Ray diffraction (XRD), thermal gravimetric analysis (TGA) and tensile profile analysis (TPA). The FTIR results provided information about the nature of the crosslinking in the films, while TGA showed that increasing the citric acid concentration reduced the physical decomposition temperature of the materials. Films containing 9% citric acid had the highest degree of esterification and crosslinking, while those containing 7% citric acid had the lowest heat‐related weight loss that correlated with the degree of crosslinking. The weight loss among all six samples was the greatest in the temperature range 260 °C–350 °C where a total of 60% weight loss occurred. The XRD results showed that films containing 3% citric acid had the lowest crystallinity while the native starch films had the highest crystallinity. The TPA analyses showed that films containing 5% citric acid had the greatest influence on improving the tensile strength and elastic modulus, while also having the best impact on lowering the elongation. Tensile strength values recorded for films containing 0%, 1%, 3%, 5%, 7% and 9% citric acid were 5.327, 7.813, 8.688, 12.855, 14.549 and 11.614 MPa. Similarly, when citric acid concentration increased from 3% to 5%, the elastic modulus significantly increased from 831.058 to 2255.691 MPa. This study demonstrated that the physicochemical properties of tapioca starch‐based films could be modified by the incorporation of citric acid.