Abstract
1. In the thermal decomposition of sodium peroxoborate within the interval 120–180°, simultaneously with the conversion of peroxide groups there is an elimination of H2O. About 25% of the oxygen is liberated into the gas phase; ∼75% remains in the substance, losing its peroxide nature. In the case of complete conversion of peroxoborate, a substance with the empirical composition NaBO2.8 was obtained. 2. The composition of the substance formed is a function of the degree of decomposition of the peroxoborate and does not depend on the temperature of decomposition within the interval 120–180°. 3. The apparent activation energies of the conversion of peroxide oxygen and the formation of H2O were determined.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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