Abstract
The decomposition of silver chromate complex with 1, 10 phenanthroline has been studied by TG/DTG/DTA method and X-ray diffraction analysis. Intermediate decomposition products have been isolated and characterized. The thermolysis of Ag2(phen)2CrO4 occurs in the two major stages: Ag2(phen)x“CrO4” as a product of the first stage and various mixtures of silver, silver chromate and silver metachromite as the final residue. The comparison of the decomposition process of the complex with that of parent Ag2CrO4 indicates that the presence of ligand changes thermal behaviour of the latter.
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