Abstract
Purity determination by calorimetry has been used to determine the rate constant of thermal decomposition of N-2,4,6-tetranitro-N-methylaniline in liquid and solid states. The ratios of the initial rates of decomposition in solid and liquid decrease when temperature increases in the region not far below the melting point. The predicted rate constants in solid state are about 10 times greater than the one estimated by Wiseman. The thermal decomposition process at lower temperatures has been used to determine the rate constant in the decay phase. Activation energy and pre-exponential factor are also presented.
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