Abstract

The thermal decomposition of Cu(I) phosphine complexes of the general types (CuXPPh3)4, [CuX(PPh3)2] and [CuX(PPh3)3] was investigated.The thermal decomposition of (CuXPPh3)4, where X denotes Cl−, Br−, I−, NO −3 and PPh3=P(C6H5)3, occurs with formation of a phosphine oxide intermediate. For the remaining complexes this intermediate was not proved in the thermal decomposition.

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