Abstract

The thermal decomposition reactions of [Co(NH3)6]Cl3 were determined in dynamic argon and air atmospheres. The investigations were carried out with simultaneous TG-DTG-DTA measurements under non-isothermal conditions, thermogravimetry under quasi-isothermal conditions, reflectance spectroscopy, absorption spectroscopy, X-ray diffraction and chemical analysis. The data show that the thermal decomposition of [Co(NH3)6]Cl3 occurs in three and four stages in argon and air atmospheres, respectively. The determined sequences are in agreement with that proposed by Simons and Wendlandt [2, 5].

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