Abstract
AbstractThe thermal decomposition and vaporisation of ammonium sulphate, (NH4)2SO4, is shown to take place via two distinct sets of reactions. In the first, ammonium pyrosulphate, (NH4)2S2O7, is the primary condensed phase product: 2(NH4)2SO4 ← (NH4)2S2O7+2NH3+H2OThe second stage concerns the decomposition of the pyrosulphate. Ammonia, sulphur dioxide, nitrogen and water are the major products, the dominant reaction being 3(NH4)2S2O7 ← 2NH3+6SO2+2N2+9H2O
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