Abstract
Differential thermogravimetric, and x-ray photoelectron spectral, as well as diffraction, analyses were applied to investigate anodic coatings formed under electric-breakdown conditions in electrolytes containing polyphosphate manganese complexes. It is shown that annealing at temperatures of up to 1000°C does not affect the concentration of elements in coatings, but is conducive to crystallizing Na0.23TiO2-bronze, manganese pyrophosphate Mn2P2O7 , sodium, as well as manganese, titanophosphates NaTi2(PO4)3 and Mn(II)Mn(III)Ti(PO4)3 , respectively.
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