Thermal batteries with ceramic felt separators – Part 2: Ionic conductivity, electrochemical and mechanical properties

Abstract

In this Part 2, the ionic conductivity of molten salt electrolytes, the electrochemical properties of single cells containing a ceramic separator infiltrated with an electrolyte, and the mechanical strength of the electrolyte layer are compared with those of the conventional pellet-pressed structure. The ionic conductivity for the molten electrolyte is higher than that of the previous report for both LiCl-KCl and LiF-LiCl-LiBr electrolytes, which is explained by the decrease in contact resistance using a graphite electrode instead of stainless steel. The electrochemical performance of the single cells containing a ceramic felt separator assembled with Li(Si)/FeS2 electrodes shows longer operating time to a cut off voltage of 1.3V compared to the conventional MgO-contained single cell. In addition, the flexural strength of the electrolyte layer with the ceramic felt separators is in the range of 2.80–6.29kgfcm−2, which is incomparable to that (=0.01kgfcm−2) of the pellet-pressed conventional separator. These findings suggest that the ceramic felt separator can be an alternative to mitigate the current problems of pellet-pressed structure in thermal batteries, enhancing the mechanical strength and electrochemical properties.