Thermal batteries with ceramic felt separators – Part 1: Wetting, loading behavior and chemical stability

Abstract

The use of a thermally and chemically stable ceramic felt separator for thermal batteries is believed to enhance the reliability by minimizing the sudden failure of an electrolyte upon shock compared to the conventional pellet-pressed one. To achieve desirable electrochemical properties for applications in thermal batteries, the separator should hold a sufficient amount of molten electrolyte with a minimal leakage to prevent physical contact between the cathode and anode. In addition, the chemical stability of the separator materials should be maintained under a very reactive molten Li-salt electrolyte environment to confer high ionic conductivity and reliability. To assess the feasibility of 3 types of ceramic felt as a separator for thermal batteries, 2 types of Al2O3 felt with different porosity and one ZrO2 felt are examined using binary LiCl-KCl and ternary LiF-LiCl-LiBr as the electrolytes. This Part 1 explains the wetting, loading and leakage behaviors of the ceramic felts for molten electrolytes along with the chemical stability. The ionic conductivity of the electrolytes and electrochemical properties of the resulting thermal batteries will be presented in Part 2.