Abstract

The first stages of the interaction between InP substrates and gases used in chemical vapor deposition processes (NH 3 , SiH 4 and O 2 ) with and without the assistance of uv illumination have been studied for the first time in an uhv environment by surface techniques. Photo-assisted NH 3 exposures lead to a nitrogen uptake in opposition to thermally-assisted exposures. Photo or thermally-assisted SiH 4 exposures partly remove the native oxide and drive silicon atoms to form covalent bonds to InP. Successive exposures to SiH 4 and O 2 build the first silica layers.

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