Abstract
In this paper, a complete solution of the mathematical model of ZLC chromatography using a Volterra integral technique is described. The model includes the effects of isotherm non-linearity, extracolumn broadening and various types of intrinsic sorption kinetics. Another attribute of the model is that it describes exactly the initial stage of the ZLC chromatographic experiment. The above effects (influence of the diffusivity, of the carrier gas flow rate and of the isotherm non-linearity) on the shape of the system response is demonstrated. The effectiveness of the model is illustrated by experimental curve fitting.
Published Version
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