Abstract

The light scattering by thin rodlike particles in a liquid subjected to shear is calculated on the basis of the Rayleigh-Gans treatment. The calculations are made for both unidirectional laminary flow and for flow of periodically alternating direction. The calculation is carried out by two methods: the interference factor P is expressed in terms of a power series of G/D, where G and D are the rate of shear and the rotatory diffusion constant, respectively, of the rod rotating around its minor axis. This treatment is applicable to sufficiently low G/D values. The result for a very wide range of rate of shear is obtained by using the Peterlin distribution function of particle axis. Numerical calculation shows that both results agree in a region of G/D below about two if the axial ratio is large enough. The theoretical results appear to agree with the experimental ones.

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