Abstract
In this paper, we have theoretically investigated the behavior of three figures of merit which might be used to characterize ion selective electrode membranes. This has been accomplished by extending the Smith-Anderson model for calculating the electronic conductivity of particulate membranes to the case of the all solid state silver sulfide electrode, one of the simplest such systems which can be treated. The transport number of Ag + is found to be extremely sensitive to membrane composition. This result points to transport number as potentially the most useful figure of merit for ion selective membrane electrodes of this type.
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