Abstract
An iterative procedure has been developed for the numerical solution of the exact Smith–Ewart differential difference equations for a compartmentalised free-radical polymerisation reaction in the non-steady state. The procedure is of wide applicability, being capable of extension to include states of as high a radical-occupancy as is considered to be appropriate to the reaction system under consideration. The procedure is also in principle capable of application to reaction systems whose characterising parameters are time-dependent. Examples are given of results obtained using the procedure, and comparisons are made with the corresponding predictions of the Poissonian approximation described in a previous paper in this series.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.