Abstract
The dynamic range and selectivity of field flow fractionation (FFF) can be improved by using secondary chemical equilibria (SCE). SCE are established by including a macromolecular additive, which strongly interacts with the field, in the carrier. A theoretical evaluation of SCE-FFF for small solutes is presented. The effects of field strength, additive concentration, solute-additive binding, and the interaction of the additive with the external field are evaluated.
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