Abstract
For the first time, wall paintings of 20th century Russian artists in Bulgaria were analysed by means of complementary analytical methods. Representative samples collected from the Russian church St. Nicholas in Sofia, decorated by the famous Russian artists Vasily Perminov, Michail Maletski and Nikolay Shelehov during different periods of time, were examined by means of micro-Raman spectroscopy, attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy and X-Ray fluorescence (XRF). The results of the study reveal that colourful palette was achieved by using various pigment mixtures of traditional and modern synthetic pigment as titanium white, barium white, calcite, chrome green, green earth, hematite, ultramarine, madder lake, carbon black, vermilion, Naples yellow. The analysis of the paint binders allow to conclude that Maletski and Shelehov have used egg tempera as painting technique, while Perminov has worked in two painting techniques - oil and egg tempera.
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