The use of one-electron quantum numbers to describe polyelectronic systems

Abstract

Atomic states are rigorously characterized by the total orbital angular momentum and the total spin angular momentum, but chemists persist in the use of electron configurations based on one-electron quantum numbers and simplified rules for predicting ground state configurations. This practice is defended against two lines of criticism, and its use in teaching chemistry is encouraged with the claim that the inductive approach of Mendeleev and the deductive approach initiated by Schrodinger compose the consummate example of that interaction of empirical and rational epistemologies that defines how chemists think.