Abstract
1. In situ 1H NMR spectroscopy and using parahydrogen (p-H 2) allows to characterize the stereochemistry of suitable hydrogenation reactions instantaneously. 2. The rhodium(I)-catalyzed homogeneous hydrogenation of the unsaturated racemic alcohols ( R,S)-2-(1-hydroxy-ethyl)-acrylic acid methyl ester ( I) and ( R,S)-2-methoxy-1-phenyl-buta-2,3-dien-1-ol ( II) leads to the formation of different diastereomeric products which can be distinguished unambiguously due to their characteristic polarization multiplets.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
