Abstract
Microporous- and mesoporous-activated carbons were produced from longan seed biomass through physical activation with CO2 under the same activation conditions of time and temperature. The specially prepared mesoporous carbon showed the maximum porous properties with the specific surface area of 1773 m2/g and mesopore volume of 0.474 cm3/g which accounts for 44.1% of the total pore volume. These activated carbons were utilized as porous adsorbents for the removal of methylene blue (MB) from an aqueous solution and their effectiveness was evaluated for both the adsorption kinetics and capacity. The adsorption kinetic data of MB were analyzed by the pseudo-first-order model, the pseudo-second-order model, and the pore-diffusion model equations. It was found that the adsorption kinetic behavior for all carbons tested was best described by the pseudo-second-order model. The effective pore diffusivity (De) derived from the pore-diffusion model had the values of 4.657 × 10−7–6.014 × 10−7 cm2/s and 4.668 × 10−7–19.920 × 10−7 cm2/s for the microporous- and mesoporous-activated carbons, respectively. Three well-known adsorption models, namely the Langmuir, Freundlich and Redlich–Peterson equations were tested with the experimental MB adsorption isotherms, and the results showed that the Redlich–Peterson model provided the overall best fitting of the isotherm data. In addition, the maximum capacity for MB adsorption of 1000 mg/g was achieved with the mesoporous carbon having the largest surface area and pore volume. The initial pH of MB solution had virtually no effect on the adsorption capacity and removal efficiency of the methylene blue dye. Increasing temperature over the range from 35 to 55 °C increased the adsorption of methylene blue, presumably caused by the increase in the diffusion rate of methylene blue to the adsorption sites that could promote the interaction frequency between the adsorbent surface and the adsorbate molecules. Overall, the high surface area mesoporous carbon was superior to the microporous carbon in view of the adsorption kinetics and capacity, when both carbons were used for the removal of MB from an aqueous solution.
Highlights
Adsorption has gained increasing acceptance in the separation and purification processes for both gas and liquid systems, due to its process simplicity, less energy consumption, high separation efficiency at trace concentrations, low maintenance cost, and adsorbent reusability [1,2]
The present work was aimed to study and compare the equilibrium and kinetics of methylene blue adsorption from aqueous solution by a microporous-activated carbon, and a high surface area mesoporous-activated carbon prepared from longan fruit seed
C0 where qt is the adsorption capacity of methylene blue (MB) at time t, Re (%) is the removal efficiency of MB dye, C0 and C are the initial concentration and the concentration at time t of MB, respectively, V is the volume of the solution (L), and W is the amount of longan seed-activated carbon employed (g)
Summary
Adsorption has gained increasing acceptance in the separation and purification processes for both gas and liquid systems, due to its process simplicity, less energy consumption, high separation efficiency at trace concentrations, low maintenance cost, and adsorbent reusability [1,2]. The removal of MB from industrial wastes has been reported using various methods such as electrochemical removal, photodegradation reaction, chemical coagulation, membrane filtration, and physical adsorption methods [14,15,16] Of these removing techniques, the application of adsorption utilizing low-cost adsorbents to remove this dye is an attractive process for the efficient removal of this dye, and has been the focal point of a number of investigations [4,14]. With regard to activated carbon, an understanding of the correlation between its porous properties, including the surface area and pore size distribution, and the adsorption capacity is essential for the selection of the most appropriate adsorbent for the effective removal and control of the dyes. The present work was aimed to study and compare the equilibrium and kinetics of methylene blue adsorption from aqueous solution by a microporous-activated carbon, and a high surface area mesoporous-activated carbon prepared from longan fruit seed. Different initial dye solutions required for the adsorption tests were prepared by diluting the stock solution in appropriate proportions
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