Abstract

The system NaCl-AlCl3 has been restudied by DTA, visual observation, and x-ray diffraction powder techniques for identification of crystalline phases. It was confirmed that the system contains one intermediate compound NaAlCl4 with an incongruent mp of 153 ± 0.5 °C and a region of liquid immiseibility extending from 80.25 to 99.6 mol percent AlCl3 at 191.3 °C, the monotectic temperature.

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