Abstract
1,3-H2-, 1,3-Me2-, and 1,3-Et2-4,5-Dihydroxyimidazolidine-2-thiones were synthesized and their structural peculiarities were studied. A comparative analysis of dihydroxyimidazolidine-2-thione and its carbonyl analog performed in the framework of detailed investigation of the electron density distribution in the corresponding crystals revealed the reason for different number and geometric parameters of the hydrogen bonds formed by the (thio)carbonyl groups in the crystals.
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