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https://doi.org/10.1016/s0040-4039(00)74477-7
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Cite Journal: Tetrahedron Letters |  Publication Date: Feb 1, 1991 |
 Citations: 6 |
Affiliation: Bristol-Myers Squibb (Canada)
The synthesis of an analog of the carbapenem antibiotics, the asparenomycins, is described. This analog lacks the methyl group in the 6-alkylidene side chain while a methyl group has been placed at the 1β-position. The key step involved the Lewis acid-catalyzed rearrangement of an epoxide to an allylic alcohol.
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