Abstract
AbstractTreatment of N‐heterocyclic silylene Si[N(tBu)CH]2 (1) and [(η3‐C3H5)PdCl]2 in toluene led to the formation of the mononuclear complex (η3‐C3H5)Pd{Si[N(tBu)CH]2}Cl (3), the silicon analogue to N‐heterocyclic carbene complex (η3‐C3H5)Pd{C[N(tBu)CH]2}Cl (2). Complex 3 was characterized with 1H NMR and 13C NMR. Investigation shows that (η3‐C3H5)Pd{Si[N(tBu)CH]2}Cl is an active catalyst for Heck coupling reaction of styrene with aryl bromides.
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