Abstract

A comparative study of nitrogen doping in ZnSe and ZnTe has been performed and the results suggest that dopant solubility seems to be the limiting factor, at least under our growth conditions, in obstructing degenerate p-type doping of ZnSe. In an effort to increase the nitrogen acceptor concentration in ZnSe, we have investigated the effects of Te isoelectronic impurity on the nitrogen doping concentration in ZnSe. It was found that the total nitrogen concentration and the nitrogen acceptor concentration are indeed increased, but the room temperature free hole concentration actually drops slightly. Temperature dependent transport measurements were performed and the results show a large increase in compensation ratio as well as a dramatical reduction in hole mobility. The latter is attributed to the tendency for hole localization at the isoelectronic impurity.

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