Abstract

Highly textured (Bi,Pb)2Sr2Ca2Cu3O10(Bi-2223)/Ag composite tapes have received considerable attention as high-Tc superconducting materials for electric power and high-magnetic-field applications because of their relatively high-critical current densities and their flexibility. In order to improve the performance of these tapes for many commercial applications, it is essential that the mechanisms that limit the critical current density are fully understood. Previous microscopical studies of these tapes have revealed that interfaces such as grain boundaries strongly influence the transport of large currents1. From a morphological point of view, several models have been proposed to describe potential current transport mechanisms. However, as these models consider mainly the large-scale configuration of the boundaries, the underlying mechanism controlling the properties is still unclear. In order to elucidate the exact role of grain boundaries, systematical studies on the effect of the atomic structure as well as any chemistry change that occurs at the interface are required.

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