Abstract

The benzene sorption capacity of as-synthesized and calcined MCM-41 and MCM-48 were compared. The hydrocarbon sorption capacity increases with pore diameter for the calcined versions. As-synthesized samples sorb appreciable amounts of benzene but the quantity is invariant with respect to pore diameter. The sorption of hydrocarbon by as-synthesized M41S materials is a unique feature not observed with microporous molecular sieves.

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