Abstract

Our previously proposed equation of state has been extended to mixtures. The new mixing rule requires only one binary parameter and combines two types of mixing rules: a classical mixing rule for the infinitely dilute density region, and a local mole fraction mixing rule for the no free volume region. The new mixing rule yields good agreement with experimental PVT properties of polar binary systems which contain CO 2, H 2O, MeOH and EtOH.

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