The S1neutral and D0cationic states of fluorobenzene and fluorobenzene–argon probed by ZEKE spectroscopy with partial rotational resolution

Abstract

Rotationally resolved zero electron kinetic energy (ZEKE) spectra of fluorobenzene and fluorobenzene–argon have been investigated using a spectator orbital model to interpret the rotational structure. Unlike a frozen core model this model relates to the electronic structure in both final and initial states. A new ZEKE electron detection scheme was employed to record ZEKE excitation spectra as a function of the S1 ← S0 excitation laser photon energy, with fixed photon energy of the ionization laser. These ZEKE excitation spectra are a sensitive probe of the rotational constants of all three states involved, the S0 and S1 of the neutral and the D0 of the cation. The rotational constants of the fluorobenzene cation were found to be A+ = 5406.8 ± 5.3 MHz, B+ = 2689.7 ± 3.5 MHz, and C+ = 1812.1 ± 1.8 MHz. The rotational constants for the argon complex were found to be A′ = 1773.3 ± 1.7 MHz, B′ = 1148.9 ± 1.4 MHz, and C′ = 996.83 ± 0.98 MHz in the intermediate S1 state, and A+ = 1848.8 ± 1.8 MHz, B+ = 1076.6 ± 1.4 MHz, and C+ = 908.37 ± 0.89 MHz in the cationic D0 state. Two structural parameters of the complex were derived from these rotational constants, the distance between the argon atom and the aromatic ring, rz and the distance in the plane of the aromatic ring between the centre of mass and the argon atom rx. These two parameters were determined as rx = 0.78 A and rz = 3.33 A in the S1 state and rx = 0.36 A and rz = 3.76 A in the D0 state.