The roles of low molecular compounds on the light aromatics formation during different rank coal pyrolysis

Abstract

Light aromatic hydrocarbons are an important by-product of the coal chemical industry. The structure and properties of low molecular compounds (LMCs) embedded in coal are different from those of coal macromolecular skeleton structure, they have important effects on the coal pyrolysis. In this paper, the roles of LMCs on the formation of light aromatics during coal pyrolysis are investigated. The results show that LMCs have little effect on the thermal weight loss behavior of the three coals, but they can influence the carbon structure distribution of coals. The main source of light aromatics from coal pyrolysis is derived from thermal cracking of the coal macromolecular framework. And also the LMCs will be pyrolyzed to generate light aromatics. The total amount of BTEXN from extracts of Shengli coal (SL), Pingshuo coal (PS) and Hexi coal (HX) pyrolysis was 15%, 91%, and 12% of that of raw coal. The alkylbenzenes, naphthalene series, and PAHs can be cracked to form light aromatics. The long chain and cyclic aliphatic compounds can not only provide hydrogen for the free radical fragment of aromatics but also generate light aromatics. And the content of these compounds in the extracts of PS is higher than that of the other two coals. Due to the complexity of the combination between LMCs and coal structure, the extracts are easier to generate light aromatics than LMCs embedded in coal during pyrolysis. Because the composition and content of low molecules in coal with different metamorphic degrees are different, the effects of LMCs on the pyrolysis of low rank coal are more obvious compared with high rank coal.