The Role of Si and Cu Alloying Elements on the Dendritic Growth and Microhardness in Horizontally Solidified Binary and Multicomponent Aluminum-Based Alloys

Abstract

Horizontal directional solidification (HDS) experiments were carried out with Al-3wtpctCu, Al-3wtpctSi, and Al- 3wtpctCu-5.5wtpctSi alloys in order to analyze the interrelation between the secondary dendrite arm spacing (λ 2) and microhardness (HV). A water-cooled horizontal directional solidification device was applied. Microstructural characterization has been carried out using traditional techniques of metallography, optical, and SEM microscopy. The ThermoCalc software was used to generate the phase equilibrium diagrams as a function of Cu and Si for the analyzed alloys. The effects of Si and Cu elements on the λ 2 and HV evolution of the hypoeutectic binary Al-Cu and Al-Si alloys have been analyzed as well as the addition of Si in the formation of ternary Al-Cu-Si alloy. The secondary dendrite arm spacing was correlated with local solidification thermal parameters such as growth rate (V L), cooling rate (T R), and local solidification time (t SL). This has allowed to observe that power experimental functions given by λ 2 = Constant (V L)−2/3, λ 2 = Constant (T R)−1/3 and λ 2 = Constant (t SL)1/3 may represent growth laws of λ 2 with corresponding thermal parameters for investigated alloys. Hall–Petch equations have also been used to characterize the dependence of HV with λ 2. A comparative analysis is performed between λ 2 experimental values obtained in this study for Al-3wtpctCu-5.5wtpctSi alloy and the only theoretical model from the literature that has been proposed to predict the λ 2 growth in multicomponent alloys. Comparisons with literature results for upward directional solidification were also performed.