Abstract
The individual separation of lanthanides is very complex due to the similarities between these elements. Ion-exchange separations with carboxylic acids are widely studied, but the importance of pH is overlooked. This study used citric acid to evaluate Lu and Yb separation with Dowex 50W-X8. The separation was monitored by X-ray fluorescence. Five new structures of Lu and Yb citrates are proposed. Better separation occurs when the pH of the ligand is pH 4.5, where a mononuclear structure is formed. Conversely, polynuclear structures are formed at higher pH, and separation fails. X-ray diffraction reveals different phases at each pH value, and FTIR results support the proposed structures.
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