The role of organic amendment in soils affected by residual pollution of potentially harmful elements

Abstract

The addition of organic amendment in soils affected by residual pollution of potentially harmful elements (PHEs) is evaluated. The area was polluted twenty years ago and remediation actions were intensively applied, but evidence of pollution are still detected in some sectors. The amendment application produces significant changes in the main soil properties and modifies the mobility and availability of the pollutants. In general, Cu, Zn, Cd and Pb, showed a significant reduction in soluble and exchangeable forms after the vermicompost addition (percentage of reduction ranging from 59% for soluble Pb to 95% for exchangeable Zn), both in highly (UVS) as in moderately (VS1) polluted soils. This reduction is strongly related to the rise in OC content and pH. Arsenic presented no significant reduction or even an increase in soluble forms in moderately polluted soils (VS1), where the competing effects of OC and phosphorous could be responsible for this increase. Pb also showed an increase in availability after vermicompost application, probably related to the competing effect of Mg2+ coming from the organic amendment. The less mobile forms (those extracted with oxalic-oxalate, pyrophosphate and EDTA), indicate that vermicompost application reduce medium-long term mobility to similar values of those found in less polluted soils (VS2); anyway, an increase in available forms of Pb and As was detected in some cases, indicating a potential risk of toxicity that should be monitored over time.