Abstract

Abstract Stress-relaxation data are presented for two commercial grades of ABS and an ABS-polycarbonate blend over a temperature range which includes the glassy, transition, and entanglement regions. Reduced master curves and the shift factor, aT, are obtained and compared to data for fractionated polystyrene and polycarbonate; the principle of time-temperature superposition is shown to be as applicable to the relaxation data for these heterogeneous polymers as to similar data for homogeneous polymers. Compared with homogeneous polymers, the reduced curves for the composites are different in several ways: A slightly larger negative slope in the glassy region, a more diffuse transition region, a higher and broader entanglement plateau, and a smaller negative slope in the flow region are noted. For the two ABS polymers, the temperature dependences of aT are about that of a homogeneous polymer with an equivalent Tg, indicating that the discrete rubber particles do not alter the relative relaxational behavior...

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